🏆 FREE A* Grade Chemistry Notes Download: IGCSE, O-LEVEL, AQA, Edexcel (2026 Syllabus onwards)
🚀 YOUR CHEMISTRY MASTERY STARTS HERE: Ultra-Premium, Free Lecture Notes for Sure Top Grades in Exams
| Chemistry Topics (The A* Essentials) | Core Concepts | Exam Board Coverage | Instant Download |
|---|---|---|---|
| **Moles** | Stoichiometry, **Limiting Reactant**, Percentage Yield, Molar Mass, **Concentration Calculation** | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Chemical Bonding** | Ionic, Covalent, Metallic, **Giant Structures**, Dot-and-Cross Diagrams | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Organic Chemistry (Part 1)** | Alkanes, Alkenes, **Isomers**, Homologous Series, Unsaturated vs. Saturated | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Organic Chem (Part 2)** | Alcohols, Carboxylic Acids, Esters, **Polymerization**, Fermentation | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Electrolysis** | **Selective Discharge**, Anode/Cathode, **Half-Equations**, Electroplating | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Redox** | **Oxidation/Reduction**, **OIL RIG**, Oxidizing Agent, Half-Equations | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Chemical Energetics** | Exothermic, Endothermic, **Activation Energy**, $\Delta\text{H}$, Energy Profile Diagrams | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Acids, Bases and Salts** | $\text{pH}$ Scale, Neutralization, **Salt Preparation (Titration)**, Alkali vs. Base | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **The Periodic Table** | **Group Trends** (1, 7, 0), Reactivity Trends, Periodicity | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Atoms, Elements and Compounds** | **Isotopes**, Protons, Neutrons, Electrons, Relative Atomic Mass ($\text{A}_r$) | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **States of Matter (Part 1)** | **Kinetic Particle Theory**, Diffusion, Brownian Motion, Changes of State | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **States of Matter (Part 2)** | Advanced Particle Behaviour, Gas Properties, Intermolecular Forces | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Metals (Part 1)** | **Reactivity Series**, Extraction by Carbon/Electrolysis, Displacement Reactions | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Metals (Part 2)** | **Rusting** (Conditions and Prevention), **Sacrificial Protection**, Iron Extraction | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Experimental Techniques** | Filtration, Distillation (Simple/Fractional), **Chromatography**, Purity Tests | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Formula** | **Valency Rules**, Naming Compounds, Writing Chemical Formulae | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Formulae** | **Empirical Formula** Calculation, Molecular Formula Derivation, $\text{M}_r$ | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Reactions** | **Rates of Reaction**, **Collision Theory**, Factors Affecting Rate (T, C, SA, Catalyst) | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Oxygen and Air** | Atmospheric Composition, **Air Pollution** ($\text{SO}_2, \text{NO}_x$), **Acid Rain** Formation | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
| **Hydrogen and Water** | Water Treatment (Chlorination), Properties of Hydrogen, Fuel Use, Reduction | CAIE 0620/5070 AQA Edexcel | Download PDF Free |
🚀 WELCOME TO CAMBRIDGE CLASSROOM: UNLOCK YOUR CHEMISTRY POTENTIAL
STOP WONDERING HOW TO GET AN A*. START WORKING SMARTER.
Are you aiming for the absolute top position (A*/Grade 9) in your O-Level Chemistry (5070) or IGCSE Chemistry (0620/0971) examinations? Whether you’re studying the Cambridge (CAIE), AQA, Edexcel International, or Oxford AQA syllabus, the challenge remains the same: mastering complex concepts like Moles, Organic Chemistry, and Redox Reactions with flawless precision.
Most students struggle because standard revision materials are dull, academic, and fail to address the underlying conceptual hurdles. We’ve changed that. This 5000+ word, SEO-optimized, High-CTR article is your gateway to accessing the best, humanized, and syllabus-aligned lecture notes available online. We’ve embedded the answers to the most searched O-Level Chemistry questions directly into the content, ensuring you find us, and more importantly, find success!
✨ THE CAMBRIDGE CLASSROOM GUARANTEE: YOUR A* TOOLKIT
We don’t just provide notes; we provide a learning strategy optimized for peak exam performance in 2026 and beyond.
| Feature | Why It Guarantees Success | High CTR Keyword Relevance |
| Humanized Writing | Complex science translated into simple, memorable analogies and language. | Easy IGCSE Chemistry Notes, Simple Moles Calculation |
| Maximal Keyword Density | Targets over 100 long-tail and short-tail search terms to dominate Google rankings. | O-Level Chemistry Past Papers PDF, AQA Chemistry Notes Free |
| Syllabus Overlap (2026 Ready) | Perfect for CAIE, AQA 9-1, Edexcel IGCSE, and Oxford syllabi—no topic is missed. | Best Chemistry Study Guide 2026, IGCSE 0620 Notes |
| Conceptual Clarity | Focuses on why concepts work, not just what they are (e.g., why $\text{H}^+$ is acidic). | How to master Organic Chemistry, Electrolysis explained simply |
📚 SECTION 1: THE FOUNDATIONAL BUILDING BLOCKS OF CHEMISTRY
Mastering the basics of Atomic Structure, Bonding, and Formulae is non-negotiable. These concepts lay the groundwork for high-scoring topics like Stoichiometry and Redox.
1.1 Atoms, Elements, and Compounds: The Fundamentals
Most Searched Question: “What are the definitions of Atom, Element, Compound, and Isotope for IGCSE?”
An Atom is the smallest particle of an element, defined by its nucleus containing Protons (positive, defines the element’s identity) and Neutrons (neutral). The surrounding Electrons (negative) determine its reactivity.
An Element is a pure substance made up of only one type of atom (e.g., Gold). A Compound is formed when two or more different elements are chemically bonded (e.g., water, $\text{H}_2\text{O}$).
The crucial detail: Isotopes are atoms of the same element (same number of protons) but with different numbers of neutrons, resulting in different mass numbers (e.g., Carbon-12 and Carbon-14).
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Atoms, Elements and Compounds | Proton Number, Nucleon Number, Isotopes, Relative Atomic Mass ($A_r$), Mixtures vs. Compounds | Download PDF: Atoms, Elements and Compounds |
1.2 Chemical Bonding: The Glue of Chemistry
Most Searched Question: “How do I correctly draw Dot-and-Cross diagrams for Ionic and Covalent Bonding?”
Chemical Bonding dictates the structure and properties of every substance.
Ionic Bonding (The Great Exchange): Occurs between a Metal (loses electrons to form a positive cation) and a Non-Metal (gains electrons to form a negative anion). The strong electrostatic attraction forms a Giant Ionic Lattice (high melting points, conducts electricity only when molten or aqueous).
Covalent Bonding (The Sharing Economy): Occurs between two Non-Metals who share electrons to achieve a stable outer shell. This forms Simple Molecular Structures (low melting/boiling points, poor conductors) or Giant Molecular Structures (e.g., Diamond/Graphite—exceptionally high melting points).
Metallic Bonding: Metal atoms in a lattice surrounded by a ‘sea’ of delocalized electrons. This explains why metals are excellent conductors, malleable, and ductile.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Chemical Bonding | Ionic, Covalent, Metallic Bonds, Dot-and-Cross Diagrams, Giant Molecular Structure, Properties vs. Structure | Download PDF: Chemical Bonding |
1.3 Formulae and Equations: The Language of Chemistry
Most Searched Question: “What is the simple rule for writing chemical formulae using valency?”
Writing correct chemical formulae is a prerequisite for every calculation in Chemistry. We use the ‘Criss-Cross’ Method based on the valency (combining power) of the ions to determine the simplest ratio of atoms. For example, $\text{Al}^{3+}$ and $\text{O}^{2-}$ combine to form $\text{Al}_2\text{O}_3$.
Empirical Formula (The Simplest Ratio): The simplest whole number ratio of atoms in a compound.
Molecular Formula (The True Count): The actual number of atoms of each element in a molecule.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Formula | Valency Rules, Naming Inorganic Compounds, Writing Ionic and Covalent Formulae | Download PDF: Formula |
| Formulae | Empirical Formula Calculation, Molecular Formula Determination, Relative Formula Mass ($M_r$) | Download PDF: Formulae |
🧠 SECTION 2: THE CALCULATION POWERHOUSE – MOLES, STOICHIOMETRY, AND ENERGETICS
These are the topics that separate an A from an A*. Precision and conceptual understanding are critical here.
2.1 Moles (Stoichiometry): The Central Calculation
Most Searched Question: “How to calculate the moles of a substance and the limiting reactant easily?”
The Mole is simply a unit of amount, defined by Avogadro’s constant ($6.02 \times 10^{23}$ particles). Mastery of Moles requires recognizing the three primary equations and knowing when to apply them:
Mass-to-Moles: $\text{Moles} = \frac{\text{Mass (g)}}{\text{Relative Formula Mass } (M_r)}$
Concentration-to-Moles: $\text{Moles} = \text{Concentration } (\text{mol}/\text{dm}^3) \times \text{Volume } (\text{dm}^3)$
Gas Volume-to-Moles (RT/STP): $\text{Moles} = \frac{\text{Volume of Gas } (\text{dm}^3)}{24 \text{ or } 22.4 \text{ dm}^3}$
Our notes provide a step-by-step Moles Calculation Flowchart that simplifies complex problems involving reacting masses, concentration, and percentage yield into a logical sequence. Limiting Reactant is simplified by comparing the actual mole ratio to the required mole ratio from the balanced equation.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Moles | Avogadro’s Constant, Molar Volume, Limiting Reactants, Percentage Yield, Concentration Calculations, Titration Setup | Download PDF: Moles |
2.2 Chemical Energetics: Understanding Energy Changes
Most Searched Question: “What are the differences between Exothermic and Endothermic reactions, and how do I draw an Energy Profile Diagram?”
All chemical reactions involve energy changes.
Exothermic (Energy EXITING): Releases heat energy to the surroundings, causing the temperature to increase. Products have less energy than reactants ($\Delta\text{H}$ is negative). (e.g., Combustion)
Endothermic (Energy ENTERING): Absorbs heat energy from the surroundings, causing the temperature to decrease. Products have more energy than reactants ($\Delta\text{H}$ is positive). (e.g., Photosynthesis)
The Energy Profile Diagram is crucial. It visualizes the energy pathway, clearly showing the Activation Energy ($\text{E}_a$)—the minimum energy required to start the reaction. Our notes use clear analogies to explain how catalysts lower this “energy barrier.”
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Chemical Energetics | Exothermic/Endothermic, Enthalpy Change ($\Delta\text{H}$), Activation Energy, Bond Breaking (Endo) vs. Bond Making (Exo), Catalysis | Download PDF: Chemical Energetics |
🔋 SECTION 3: THE HIGH-LEVEL CHALLENGERS – ELECTROCHEMISTRY & ORGANIC
These advanced topics often carry the highest marks in Papers 1 and 2/3. Mastery here is the key to an A*.
3.1 Redox Reactions and Electrolysis
Most Searched Question: “What are the rules for predicting products in Electrolysis, and how do I use OIL RIG for half-equations?”
Redox (Reduction/Oxidation) is the transfer of electrons. We use the mnemonic OIL RIG:
Oxidation Is Loss (of electrons, $\text{e}^-$)
Reduction Is Gain (of electrons, $\text{e}^-$)
Electrolysis is the process of using electrical energy to force a non-spontaneous chemical reaction (Redox) to occur.
Cathode (Negative): Where Reduction occurs. Cations (positive ions) migrate here.
Anode (Positive): Where Oxidation occurs. Anions (negative ions) migrate here.
The biggest challenge is predicting products. Our notes simplify this using the Selective Discharge Rules:
At the Cathode: The least reactive metal ion is discharged (unless it is $\text{H}^+$).
At the Anode: Halide ions ($\text{Cl}^-$, $\text{Br}^-$, $\text{I}^-$) are preferentially discharged over $\text{OH}^-$ (unless the solution is very dilute).
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Redox | Oxidation States, Reducing/Oxidizing Agents, Balancing Half-Equations (essential for AQA/Edexcel) | Download PDF: Redox |
| Electrolysis | Selective Discharge Rules, Industrial Applications (e.g., Aluminium extraction, Electroplating), Molten vs. Aqueous Electrolysis | Download PDF: Electrolysis |
3.2 Organic Chemistry: The World of Carbon
Most Searched Question: “How to distinguish between Alkanes and Alkenes, and how to draw Isomers for IGCSE Chemistry?”
Organic Chemistry is the study of carbon compounds. It requires memorizing the Homologous Series and their characteristic functional groups:
| Series | Formula | Functional Group | Key Reaction |
| Alkanes | $\text{C}_n\text{H}_{2n+2}$ | Single bonds only (Saturated) | Substitution (Slow) |
| Alkenes | $\text{C}_n\text{H}_{2n}$ | $\text{C}=\text{C}$ double bond (Unsaturated) | Addition (Fast, key test) |
| Alcohols | $\text{C}_n\text{H}_{2n+1}\text{OH}$ | $\text{-OH}$ (Hydroxyl) | Oxidation |
| Carboxylic Acids | $\text{C}_n\text{H}_{2n+1}\text{COOH}$ | $\text{-COOH}$ (Carboxyl) | Neutralization |
Isomers are critical: same molecular formula, different structural formula. Our notes provide simple strategies for drawing the chain isomers of Butane ($\text{C}_4\text{H}_{10}$) and Pentane ($\text{C}_5\text{H}_{12}$).
The Alkenes Test: Unsaturated Alkenes turn orange/brown Bromine water colorless via an addition reaction, making it the definitive test to distinguish them from Alkanes.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Organic Chemistry (Part 1) | Alkanes, Alkenes, Fractional Distillation, Combustion, Isomerism, Nomenclature (Methane, Ethane, Propane, etc.) | Download PDF: Organic Chemistry Part 1 |
| Organic Chem (Part 2) | Alcohols, Carboxylic Acids, Polymers (Monomers to Polymers), Cracking, Esters, Ethanol Production | Download PDF: Organic Chem Part 2 |
🔬 SECTION 4: PRACTICAL CHEMISTRY AND ENVIRONMENTAL TOPICS
These topics are essential for Paper 3 (Practical) and Paper 4 (Alternative to Practical), often involving complex flowcharts and real-world application.
4.1 Acids, Bases and Salts: The Chemistry of $\text{pH}$
Most Searched Question: “What are the three methods for preparing a pure, dry salt sample in IGCSE?”
Acids produce $\text{H}^+$ ions in water; Alkalies produce $\text{OH}^-$ ions in water. Neutralization ($\text{H}^+ + \text{OH}^- \rightarrow \text{H}_2\text{O}$) forms a Salt and water.
Salt Preparation Methods (Crucial Exam Content):
Titration (for Soluble Salts involving Group I/Ammonium): Acid + Alkali (Neutralization), used when both reactants are soluble.
Excess Solid Addition (for most other Soluble Salts): Acid + Insoluble Base/Carbonate/Metal, filtered to remove excess solid, then evaporated/crystallized.
Precipitation (for Insoluble Salts): Mix two soluble salts, forming one insoluble salt (precipitate) which is then filtered and washed.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Acids, Bases and Salts | $\text{pH}$ Scale, Indicators, Neutralization, Definition of Alkali/Base, Salt Preparation Methods, Titration Process | Download PDF: Acids, Bases and Salts |
4.2 Experimental Techniques and Purity
Most Searched Question: “How do I choose the correct separation method (Filtration, Distillation, Chromatography)?”
Selecting the correct separation technique depends entirely on the nature of the mixture:
Filtration: Separates an insoluble solid from a liquid.
Crystallisation: Separates a soluble solid from a solution (by evaporation).
Simple Distillation: Separates a solvent from a solute (e.g., pure water from salt water).
Fractional Distillation: Separates miscible liquids with different boiling points (e.g., ethanol/water or crude oil components).
Chromatography: Separates components based on their solubility in a solvent (used to identify substances like food dyes).
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Experimental Techniques | Separation Techniques, Purity Tests (Melting/Boiling Points), Locating Agents, Rf Values, Choice of Method Flowchart | Download PDF: Experimental Techniques |
🌎 SECTION 5: METALS, ATMOSPHERE, AND CHEMICAL BEHAVIOUR
The final layer of mastery involves applying core concepts to real-world material and environmental issues.
5.1 Metals and the Reactivity Series
Most Searched Question: “How do I use the Reactivity Series to determine the method of metal extraction?”
The Reactivity Series (K $\rightarrow$ Au) determines how a metal behaves and how it must be extracted from its ore.
Highly Reactive Metals (K, Na, Ca, Mg, Al): Must be extracted by Electrolysis (expensive and energy-intensive) because they are more reactive than carbon.
Moderately Reactive Metals (Zn, Fe, Pb, Cu): Can be extracted by reduction using carbon (e.g., in a blast furnace) because they are less reactive than carbon.
Low Reactivity Metals (Ag, Au): Found uncombined (native state) in the Earth.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| Metals (Part 1) | Reactivity Series, Displacement Reactions, Alloys (properties/uses), Extraction Methods | Download PDF: Metals Part 1 |
| Metals (Part 2) | Rusting (Conditions: Oxygen and Water), Prevention Methods (Sacrificial Protection, Galvanizing), Iron Extraction (Blast Furnace) | Download PDF: Metals Part 2 |
5.2 The Periodic Table and Chemical Trends
Most Searched Question: “Explain the trend in reactivity of Group 1 vs. Group 7 elements.”
The Periodic Table organizes elements by their Proton Number and explains their properties based on electron configuration.
Group 1 (Alkali Metals): Highly reactive. Reactivity increases down the group because the outer electron is further from the nucleus and easier to lose (less attraction).
Group 7 (Halogens): Highly reactive non-metals. Reactivity decreases down the group because the increasing size makes it harder to attract an incoming electron to complete the shell.
Group 0 (Noble Gases): Inert due to a stable, full outer shell.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| The Periodic Table | Groups, Periods, Trends in Density/MP/BP/Reactivity, Properties of Transition Elements, Group 1, 7, and 0 | Download PDF: The Periodic Table |
5.3 States of Matter and Rates of Reaction
Most Searched Question: “How does the Kinetic Particle Theory explain diffusion and changes of state?”
The Kinetic Particle Theory is the foundation for explaining the properties of Solids (fixed position, vibrating), Liquids (random, close together), and Gases (random, far apart).
Diffusion: The random movement of particles from an area of high concentration to low concentration. Gases with lower relative molecular mass diffuse faster.
Rates of Reaction: The speed at which reactants are converted to products. It depends on increasing the frequency of successful collisions (those with energy $\ge$ Activation Energy). Our notes explain the impact of Temperature, Concentration, Surface Area, and Catalysts using the Collision Theory.
| Resource Name | Core Concepts Covered | Download Link (FREE PDF) |
| States of Matter (Part 1 & 2) | Kinetic Particle Theory, Brownian Motion, Diffusion Rate vs. $M_r$, Changes of State (Melting, Boiling) | Download PDF: States of Matter Part 1 |
| Reactions | Collision Theory, Factors Affecting Rate (Temperature, Concentration, Surface Area, Catalyst), Measuring Rate | Download PDF: Reactions |
| Oxygen and Air | Composition of Air, Carbon Monoxide, Sulfur Dioxide, Nitrogen Oxides ($\text{NO}_x$), Acid Rain Formation | Download PDF: Oxygen and Air |
| Hydrogen and Water | Water Treatment (Filtration, Chlorination), Properties of Hydrogen and Water, Use of Hydrogen as a Fuel | Download PDF: Hydrogen and Water |
🎯 THE 3-STEP A* STRATEGY (MAXIMIZE YOUR CTR)
To translate these notes into a top grade, adopt this structured revision methodology:
Conceptual Dive (The ‘Why’): Instead of memorizing, focus on the Humanized explanations in the notes. Why does salt dissolve? (Ions pulled apart by polar water molecules). Why do Alkenes react faster? (The double bond is a site of high electron density). Understanding the ‘why’ eliminates the need for rote memorization.
Targeted Practice (The ‘How’): Use the notes as an open-book resource while attempting targeted past paper questions on one specific topic (e.g., Moles only). This immediately shows you where your knowledge gaps are and reinforces the application of the formulas.
Cross-Linking (The ‘A* Jump’): High scorers connect topics. When reviewing Electrolysis, relate it to the Metals section (extraction) and the Redox notes (electron transfer). This multi-topic linkage is what examiners look for in the highest-level answers.
🔗 ULTIMATE DOWNLOAD LIST (SECURE YOUR 2026 SUCCESS NOW)
This is the complete list of all premium, high-quality O-Level/IGCSE Chemistry Lecture Notes optimized for the 2026/2027 syllabus. Click the links below to access your FREE PDF downloads instantly via Google Drive.
| Topic Name | Core Syllabus Focus | Download Link |
| Oxygen and Air | Environmental Chemistry, Pollution | Download PDF |
| Chemical Bonding | Structure and Properties (Ionic/Covalent) | Download PDF |
| Chemical Energetics | $\Delta\text{H}$, Exothermic/Endothermic | Download PDF |
| Experimental Techniques | Separation, Purity Tests, Lab Skills | Download PDF |
| Formula | Writing Chemical Formulae (Valency) | Download PDF |
| Formulae | Empirical and Molecular Formula | Download PDF |
| Metals (Part 1) | Reactivity Series, Extraction | Download PDF |
| Metals (Part 2) | Rusting, Iron Extraction | Download PDF |
| Moles | Stoichiometry, Calculations, Yield | Download PDF |
| Organic Chemistry (Part 1) | Alkanes, Alkenes, Isomers, Nomenclature | Download PDF |
| Reactions | Rates of Reaction, Collision Theory | Download PDF |
| Redox | Oxidation/Reduction, Half-Equations | Download PDF |
| States of Matter (Part 1) | Kinetic Theory, Diffusion, Changes of State | Download PDF |
| The Periodic Table | Group Trends, Properties of Elements | Download PDF |
| States of Matter (Part 2) | Advanced Particle Behaviour | Download PDF |
| Atoms, Elements and Compounds | Atomic Structure, Isotopes, $A_r$ | Download PDF |
| Organic Chem (Part 2) | Alcohols, Carboxylic Acids, Polymers | Download PDF |
| Acids, Bases and Salts | $\text{pH}$, Neutralization, Salt Preparation | Download PDF |
| Electrolysis | Selective Discharge, Applications | Download PDF |
| Hydrogen and Water | Water Treatment, Hydrogen Fuel | Download PDF |



















![Fundamental Concepts & States of Matter • Atom: The smallest particle of an element that can exist, made of a nucleus (protons and neutrons) and electrons orbiting it. • Element: A pure substance consisting of only one type of atom, which cannot be broken down into simpler substances by chemical means. • Compound: A substance formed when two or more different elements are chemically bonded together in a fixed ratio. • Mixture: A substance containing two or more elements or compounds not chemically bonded together. Can be separated by physical means. • Molecule: A group of two or more atoms held together by chemical bonds. • Proton: A subatomic particle found in the nucleus with a relative mass of 1 and a charge of +1. • Neutron: A subatomic particle found in the nucleus with a relative mass of 1 and no charge (0). • Electron: A subatomic particle orbiting the nucleus with a negligible relative mass and a charge of -1. • Atomic Number (Z): The number of protons in the nucleus of an atom. Defines the element. • Mass Number (A): The total number of protons and neutrons in the nucleus of an atom. • Isotopes: Atoms of the same element (same atomic number) but with different mass numbers due to a different number of neutrons. • Relative Atomic Mass ($A_r$): The weighted average mass of an atom of an element compared to $1/12$th the mass of a carbon-12 atom. • Relative Molecular Mass ($M_r$): The sum of the relative atomic masses of all atoms in one molecule of a compound. • Relative Formula Mass ($M_r$): The sum of the relative atomic masses of all atoms in the formula unit of an ionic compound. • Mole: The amount of substance that contains $6.02 \times 10^{23}$ particles (Avogadro's number). • Molar Mass: The mass of one mole of a substance, expressed in g/mol. Numerically equal to $A_r$ or $M_r$. • Empirical Formula: The simplest whole number ratio of atoms of each element in a compound. • Molecular Formula: The actual number of atoms of each element in a molecule. • Solid: Particles are closely packed in a fixed, regular arrangement, vibrate about fixed positions. Definite shape and volume. • Liquid: Particles are closely packed but randomly arranged, can slide past each other. Definite volume, no definite shape. • Gas: Particles are far apart and arranged randomly, move rapidly and randomly. No definite shape or volume. • Melting Point: The specific temperature at which a solid changes into a liquid at a given pressure. • Boiling Point: The specific temperature at which a liquid changes into a gas (vaporizes) at a given pressure. • Sublimation: The direct change of state from solid to gas without passing through the liquid phase (e.g., solid $\text{CO}_2$). • Diffusion: The net movement of particles from a region of higher concentration to a region of lower concentration, due to random motion. • Osmosis: The net movement of water molecules across a partially permeable membrane from a region of higher water potential to a region of lower water potential. 2. Structure & Bonding • Ionic Bond: The electrostatic force of attraction between oppositely charged ions, formed by the transfer of electrons from a metal to a non-metal. • Covalent Bond: A strong electrostatic force of attraction between a shared pair of electrons and the nuclei of the bonded atoms, typically between two non-metals. • Metallic Bond: The electrostatic force of attraction between positive metal ions and delocalised electrons. • Ion: An atom or group of atoms that has gained or lost electrons, resulting in a net electrical charge. • Cation: A positively charged ion (lost electrons). • Anion: A negatively charged ion (gained electrons). • Octet Rule: Atoms tend to gain, lose, or share electrons in order to achieve a full outer electron shell, typically with eight electrons. • Giant Ionic Lattice: A regular, repeating 3D arrangement of oppositely charged ions, held together by strong electrostatic forces. • Simple Molecular Structure: Molecules held together by strong covalent bonds, but with weak intermolecular forces between molecules. • Giant Covalent Structure (Macromolecular): A large structure where all atoms are held together by strong covalent bonds in a continuous network (e.g., diamond, silicon dioxide). • Allotropes: Different structural forms of the same element in the same physical state (e.g., diamond and graphite are allotropes of carbon). • Electronegativity: The power of an atom to attract the electron pair in a covalent bond to itself. • Polar Covalent Bond: A covalent bond in which electrons are shared unequally due to a difference in electronegativity between the bonded atoms. • Hydrogen Bond: A strong type of intermolecular force that occurs between molecules containing hydrogen bonded to a highly electronegative atom (N, O, F). • Van der Waals' forces: Weak intermolecular forces of attraction between all molecules, arising from temporary dipoles. 3. Stoichiometry & Chemical Calculations • Stoichiometry: The study of quantitative relationships between reactants and products in chemical reactions. • Limiting Reactant: The reactant that is completely consumed in a chemical reaction, determining the maximum amount of product that can be formed. • Excess Reactant: The reactant present in a greater amount than required to react with the limiting reactant. • Yield: The amount of product obtained from a chemical reaction. • Theoretical Yield: The maximum amount of product that can be formed from a given amount of reactants, calculated using stoichiometry. • Actual Yield: The amount of product actually obtained from a chemical reaction, usually less than the theoretical yield. • Percentage Yield: $($Actual Yield $/$ Theoretical Yield$) \times 100\%$. • Concentration: The amount of solute dissolved in a given volume of solvent or solution. Often expressed in mol/dm$^3$ (molarity) or g/dm$^3$. • Solute: The substance that dissolves in a solvent to form a solution. • Solvent: The substance in which a solute dissolves to form a solution. • Solution: A homogeneous mixture formed when a solute dissolves in a solvent. 4. Chemical Reactions & Energetics • Chemical Reaction: A process that involves rearrangement of the atomic structure of substances, resulting in the formation of new substances. • Reactants: The starting substances in a chemical reaction. • Products: The substances formed as a result of a chemical reaction. • Word Equation: An equation that uses the names of the reactants and products. • Symbol Equation: An equation that uses chemical symbols and formulae to represent reactants and products, and is balanced. • Balancing Equation: Ensuring the number of atoms of each element is the same on both sides of a chemical equation. • Redox Reaction: A reaction involving both reduction and oxidation. • Oxidation: Loss of electrons, gain of oxygen, or loss of hydrogen. Increase in oxidation state. • Reduction: Gain of electrons, loss of oxygen, or gain of hydrogen. Decrease in oxidation state. • Oxidising Agent: A substance that causes oxidation by accepting electrons (and is itself reduced). • Reducing Agent: A substance that causes reduction by donating electrons (and is itself oxidised). • Exothermic Reaction: A reaction that releases energy to the surroundings, usually as heat, causing the temperature of the surroundings to rise. $\Delta H$ is negative. • Endothermic Reaction: A reaction that absorbs energy from the surroundings, usually as heat, causing the temperature of the surroundings to fall. $\Delta H$ is positive. • Activation Energy ($E_a$): The minimum amount of energy required for reactants to collide effectively and initiate a chemical reaction. • Catalyst: A substance that increases the rate of a chemical reaction without being chemically changed itself, by providing an alternative reaction pathway with a lower activation energy. • Enthalpy Change ($\Delta H$): The heat energy change measured at constant pressure for a reaction. • Standard Enthalpy of Formation ($\Delta H_f^\circ$): The enthalpy change when one mole of a compound is formed from its constituent elements in their standard states under standard conditions. • Standard Enthalpy of Combustion ($\Delta H_c^\circ$): The enthalpy change when one mole of a substance is completely combusted in oxygen under standard conditions. • Hess's Law: The total enthalpy change for a reaction is independent of the route taken, provided the initial and final conditions are the same. 5. Rates of Reaction & Equilibrium • Rate of Reaction: The change in concentration of a reactant or product per unit time. • Collision Theory: For a reaction to occur, reactant particles must collide with sufficient energy (activation energy) and correct orientation. • Factors Affecting Rate: Concentration, pressure (for gases), surface area, temperature, and presence of a catalyst. • Reversible Reaction: A reaction where products can react to reform the original reactants, indicated by $\rightleftharpoons$. • Chemical Equilibrium: A state in a reversible reaction where the rate of the forward reaction is equal to the rate of the reverse reaction, and the concentrations of reactants and products remain constant. • Le Chatelier's Principle: If a change in conditions (temperature, pressure, concentration) is applied to a system at equilibrium, the system will shift in a direction that counteracts the change. 6. Acids, Bases & Salts • Acid: A substance that produces hydrogen ions ($H^+$) when dissolved in water (Arrhenius definition) or a proton donor (Brønsted-Lowry definition). • Base: A substance that produces hydroxide ions ($OH^-$) when dissolved in water (Arrhenius definition) or a proton acceptor (Brønsted-Lowry definition). • Alkali: A soluble base that dissolves in water to produce hydroxide ions ($OH^-$). • Salt: A compound formed when the hydrogen ion of an acid is replaced by a metal ion or an ammonium ion. • Neutralisation: The reaction between an acid and a base (or alkali) to form a salt and water. $H^+(aq) + OH^-(aq) \rightarrow H_2O(l)$. • pH: A measure of the acidity or alkalinity of a solution, defined as $-\log_{10}[H^+]$. Scale from 0 to 14. • Strong Acid: An acid that fully dissociates (ionizes) in water (e.g., HCl, $H_2SO_4$). • Weak Acid: An acid that partially dissociates (ionizes) in water (e.g., $CH_3COOH$). • Strong Base: A base that fully dissociates in water (e.g., NaOH, KOH). • Weak Base: A base that partially dissociates in water (e.g., $NH_3$). • Amphoteric: A substance that can act as both an acid and a base (e.g., aluminium oxide, water). • Titration: A quantitative chemical analysis method used to determine the unknown concentration of a reactant using a known concentration of another reactant. • Indicator: A substance that changes colour over a specific pH range, used to detect the endpoint of a titration. 7. Electrochemistry • Electrolysis: The decomposition of an ionic compound using electrical energy. Requires molten or aqueous electrolyte. • Electrolyte: An ionic compound (molten or dissolved in a solvent) that conducts electricity due to the movement of ions. • Electrodes: Conductors (usually metal or graphite) through which electricity enters and leaves the electrolyte. • Anode: The positive electrode, where oxidation occurs (anions are attracted). • Cathode: The negative electrode, where reduction occurs (cations are attracted). • Faraday's Laws of Electrolysis: Relate the amount of substance produced at an electrode to the quantity of electricity passed through the electrolyte. • Galvanic (Voltaic) Cell: An electrochemical cell that generates electrical energy from spontaneous redox reactions. • Standard Electrode Potential ($E^\circ$): The potential difference of a half-cell compared to a standard hydrogen electrode under standard conditions (1 M concentration, 1 atm pressure for gases, 298 K). • Electrochemical Series: A list of elements arranged in order of their standard electrode potentials, indicating their relative reactivity as oxidising or reducing agents. 8. The Periodic Table • Periodic Table: An arrangement of elements in order of increasing atomic number, showing periodic trends in properties. • Group: A vertical column in the periodic table, containing elements with the same number of valence electrons and similar chemical properties. • Period: A horizontal row in the periodic table, containing elements with the same number of electron shells. • Valence Electrons: Electrons in the outermost shell of an atom, involved in chemical bonding. • Alkali Metals (Group 1): Highly reactive metals, readily lose one electron to form $+1$ ions. React vigorously with water. • Alkaline Earth Metals (Group 2): Reactive metals, readily lose two electrons to form $+2$ ions. • Halogens (Group 17/7): Highly reactive non-metals, readily gain one electron to form $-1$ ions. Exist as diatomic molecules. • Noble Gases (Group 18/0): Unreactive elements with a full outer electron shell, existing as monatomic gases. • Transition Metals: Elements in the d-block of the periodic table, characterised by variable oxidation states, coloured compounds, and catalytic activity. • Metallic Character: Tendency of an element to lose electrons and form positive ions. Increases down a group, decreases across a period. • Non-metallic Character: Tendency of an element to gain electrons and form negative ions. Decreases down a group, increases across a period. • Ionisation Energy: The energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous $1+$ ions. • Electron Affinity: The energy change when one mole of electrons is added to one mole of gaseous atoms to form one mole of gaseous $1-$ ions. 9. Organic Chemistry • Organic Chemistry: The study of carbon compounds, excluding carbonates, carbides, and oxides of carbon. • Hydrocarbon: A compound containing only carbon and hydrogen atoms. • Saturated Hydrocarbon: A hydrocarbon containing only single carbon-carbon bonds (e.g., alkanes). • Unsaturated Hydrocarbon: A hydrocarbon containing one or more carbon-carbon double or triple bonds (e.g., alkenes, alkynes). • Homologous Series: A series of organic compounds with the same general formula, similar chemical properties, and showing a gradual change in physical properties. • Functional Group: A specific group of atoms within a molecule that is responsible for the characteristic chemical reactions of that molecule. • Alkane: Saturated hydrocarbons with the general formula $C_nH_{2n+2}$. Contain only single bonds. • Alkene: Unsaturated hydrocarbons with the general formula $C_nH_{2n}$. Contain at least one carbon-carbon double bond. • Alkyne: Unsaturated hydrocarbons with the general formula $C_nH_{2n-2}$. Contain at least one carbon-carbon triple bond. • Alcohol: Organic compounds containing the hydroxyl functional group ($-OH$). General formula $C_nH_{2n+1}OH$. • Carboxylic Acid: Organic compounds containing the carboxyl functional group ($-COOH$). • Ester: Organic compounds formed from the reaction of a carboxylic acid and an alcohol, containing the ester linkage ($-COO-$). • Isomers: Compounds with the same molecular formula but different structural formulae. • Structural Isomers: Isomers that differ in the arrangement of their atoms or bonds. • Addition Reaction: A reaction where an unsaturated molecule adds across a double or triple bond, forming a single product. • Substitution Reaction: A reaction where an atom or group of atoms in a molecule is replaced by another atom or group of atoms. • Polymerisation: The process of joining many small monomer molecules together to form a large polymer molecule. • Monomer: A small molecule that can be joined together to form a polymer. • Polymer: A large molecule (macromolecule) formed from many repeating monomer units. • Addition Polymerisation: Polymerisation where monomers add to one another in such a way that the polymer contains all the atoms of the monomer. Usually involves unsaturated monomers. • Condensation Polymerisation: Polymerisation where monomers join together with the elimination of a small molecule (e.g., water). • Cracking: The process of breaking down long-chain hydrocarbons into shorter, more useful hydrocarbons using heat and/or a catalyst. • Fermentation: The anaerobic respiration of yeast, converting glucose into ethanol and carbon dioxide. 10. Analytical Chemistry • Qualitative Analysis: The identification of the components of a sample. • Quantitative Analysis: The determination of the amount or concentration of a component in a sample. • Chromatography: A separation technique based on differential partitioning between a stationary phase and a mobile phase. • Retention Factor ($R_f$): In paper/thin-layer chromatography, the ratio of the distance travelled by the spot to the distance travelled by the solvent front. • Spectroscopy: The study of the interaction of electromagnetic radiation with matter. • Infrared (IR) Spectroscopy: Used to identify functional groups in organic molecules based on their absorption of IR radiation. • Mass Spectrometry: Used to determine the relative molecular mass of a compound and its fragmentation pattern to deduce structure. • Flame Test: A qualitative test for the presence of certain metal ions, which produce characteristic colours when heated in a flame.](https://i0.wp.com/cambridgeclassroom.com/wp-content/uploads/2024/03/White-And-Purple-Modern-Online-Graphic-Design-Courses-Instagram-Post-4.png?resize=150%2C150&ssl=1)
