Group 1 Alkali Metals – Essential Properties & Violent Reactions for Cambridge IGCSE & O Level Chemistry
Secure your A* by mastering the most reactive metal group on the **cambridge periodic table**: The **Alkali Metals** (Lithium, Sodium, Potassium).
A*-Grade Internal Study Hub (Maximize Your Links!):
Periodic Table Chapter (Pillars → Chapters) | Group 1 Ultra Premium Notes (Syllabus → Notes) | Group 1 Redox Reactions (Notes → Crash Course) | Metal Oxide/Hydroxide Products Course (Pillars → Chapters) | A-Grade Exam Action Plan (Tips Pages → Crash Course)1. Defining the Group 1 Metals (The Exam-Centred Definition)
The **Alkali Metals** are the elements in **Group 1** of the **periodic table of elements cambridge igcse** (excluding Hydrogen). This family includes Lithium (Li), Sodium (Na), and Potassium (K)—the most commonly tested elements.
Alkali Metals (Concise Definition)
These are soft, highly **reactive metals** characterised by having only **one electron** in their outermost shell (valence shell). They readily lose this single electron to form a stable cation with a charge of **+1** (e.g., $Na^+$), making them powerful reducing agents.
Their position in the **cambridge periodic table** in Group 1 is the key to all their properties.
Key Physical Properties (What to Write in Paper 1 & 2)
- They are **Soft Metals** (can be cut with a knife).
- They have relatively **Low Melting Points and Boiling Points** which decrease down the group.
- They have **Low Density** (Lithium, Sodium, and Potassium float on water).
- They are stored under oil to prevent reaction with **Oxygen** and **Water** in the air (a common exam question!).
2. The Critical Reactivity Trend: Down the Group
Understanding the trend in reactivity is the most high-yield topic for **Group 1** questions.
Reactivity Trend (Exam Rule)
Reactivity **increases** as you move down **Group 1** (from Lithium to Caesium).
Reason: Moving down the group, the atom size increases, and the single valence electron is further from the positively charged nucleus. This weakens the electrostatic attraction, making it easier to lose the electron. The easier an atom loses its electron, the more **reactive** it is.
This trend is directly related to the concept of electron shielding, a core pillar in understanding the **cambridge periodic table as level** or IGCSE content.
Remembering Groups & Periods with a Song!
3. Key Chemical Reactions (The Equations You Must Know)
The **alkali metals** are characterised by their vigorous reactions. You must be able to state the observations and write the balanced chemical equations.
Reaction with Cold Water
All **Group 1 metals** react vigorously with water, producing a metal hydroxide (an **alkali**) and hydrogen gas. This is a classic demonstration of their reactivity.
- Equation (General): $2M(s) + 2H_2O(l) \rightarrow 2MOH(aq) + H_2(g)$
- Example (Sodium): $2Na(s) + 2H_2O(l) \rightarrow 2NaOH(aq) + H_2(g)$
- Observations: The metal floats, melts (for Na and K), moves rapidly, fizzes (hydrogen gas), and the resulting solution turns Universal Indicator blue/purple (due to the **alkali** product, e.g., Sodium Hydroxide).
Reaction with Oxygen
When heated, **alkali metals** burn rapidly in oxygen to form metal oxides.
- Equation (General): $4M(s) + O_2(g) \rightarrow 2M_2O(s)$
- Example (Lithium): $4Li(s) + O_2(g) \rightarrow 2Li_2O(s)$ (Note: Different metals can form different oxides, but $M_2O$ is the expected IGCSE/O Level standard oxide).
4. Exam-Focused Practice and Support
To truly secure your A*, you must practice applying this knowledge, especially in practical and calculation-based papers.
O Level Paper 4 Solution (5070)
IGCSE Paper 6 Solution (0620)
- **Step 1: Theory (Notes):** Master the reactivity trend reason (electron loss). See our Definitive Notes.
- **Step 2: Reactions (Equations):** Memorise the water reaction equation and observations.
- **Step 3: Exam Tips:** Learn how to structure your answers for 4-mark trend questions. Check the A-Grade Action Plan.
Group 1 Revision Timeline
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